Browsing by Author "Nouar, Farid"
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Item Exceptional stability and high hydrogen uptake in hydrogen-bonded metal-organic cubes possessing ACO and AST zeolite-like topologies(American Chemical Society, 2009) Sava, Dorina F.; Kravtsov, Victor Ch.; Eckert, Juergen; Eubank, Jarrod F.; Nouar, Farid; Eddaoudi, MohamedA novel approach for targeting zeolite-like metal-organic frameworks (ZMOFs) that utilizes metal-organic cubes and are regarded as double four-membered rings (d4Rs) and are composite building units (BUs) in traditional inorganic zeolites are reported. The implimentation of the new method is demonstrated by two ZMOFs with ACO and AST zeolite-like topologies constructed from d4R BUs exclusively held together by hydrogen bonds.Item Quest for zeolite-like metal-organic frameworks: on pyrimidinecarboxylate bis-chelating bridging ligands(American Chemical Society, 2008) Sava, Dorina F.; Kravtsov, Victor Ch.; Nouar, Farid; Wojtas, Lukasz; Eubank, Jarrod F.; Eddaoudi, MohamedTwo novel porous zeolitelike metal−organic frameworks (ZMOFs) were constructed via the single metal ion-based molecular building block approach from rigid and directional tetrahedral building units and pyrimidinecarboxylate bridging ligands; their ion exchange and hydrogen sorption properties were evaluated.