Poly(methyl methacrylate) composites of copper-4,4′-trimethylenedipyridine

dc.contributor.authorLiu, Shisi
dc.contributor.authorAnanthoji, Ramakanth
dc.contributor.authorHan, Sungyub
dc.contributor.authorKnudsen, Bernard
dc.contributor.authorLi, Xiao
dc.contributor.authorWojtas, Lukasz
dc.contributor.authorMassing, Justin
dc.contributor.authorGauthier, Carmen Valdez
dc.contributor.authorHarmon, Julie P.
dc.date.accessioned2017-04-06T22:33:39Z
dc.date.available2017-04-06T22:33:39Z
dc.date.issued2012-07
dc.description.abstractA series of poly(methyl methacrylate) (PMMA) composites were prepared with a novel one dimensional coordination polymer copper-4,4′-trimethylenedipyridine (CU-TMDP). The CU-TMDP was sonicated in a methyl methacrylate monomer and polymerized in situ. Thermal, mechanical and optical properties of CU-TMDP–PMMA composites were probed via optical microscopy, Raman spectroscopy, differential scanning calorimetry (DSC), microhardness, and dynamic mechanical analysis (DMA). The CU-TMDP was characterized by X-ray crystallography. The functionality of the CU-TMDP interacted with the polymer matrix such that mechanical properties are tuned by varying CU-TMDP loadings. The data point to the fact that interactions are primarily due to London dispersion forces or dipole–dipole interactions. This initial study forms the basis for future applications requiring tailored mechanical properties.en_US
dc.identifier.citationLiu, S., Ananthoji, R., Han, S., Knudsen, B., Li, X., Wojtas, L., & ... Harmon, J. P. (2012). Poly(methyl methacrylate) composites of copper-4,4′-trimethylenedipyridine. New Journal Of Chemistry, 36(7), 1449-1456. doi:10.1039/c2nj20745aen_US
dc.identifier.issn1144-0546
dc.identifier.urihttp://hdl.handle.net/11416/183
dc.identifier.urihttps://search.ebscohost.com/login.aspx?direct=true&AuthType=shib&db=asn&AN=100901728&site=eds-live&scope=site&custid=s5615486
dc.publisherNew Journal of Chemistryen_US
dc.subjectPolymethylmethacrylateen_US
dc.subjectCopperen_US
dc.subjectPyridineen_US
dc.subjectCoordination polymersen_US
dc.subjectComposite materialsen_US
dc.subjectPolymerizationen_US
dc.subjectPolymers -- Mechanical propertiesen_US
dc.subjectPolymers -- Thermal propertiesen_US
dc.titlePoly(methyl methacrylate) composites of copper-4,4′-trimethylenedipyridineen_US
dc.typeArticleen_US

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