Enantioenrichment of racemic BINOL by way of excited state proton transfer

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dc.contributor.authorAyad, Suliman
dc.contributor.authorPosey, Victoria
dc.contributor.authorDas, Anjan
dc.contributor.authorMontgomery, Jason M.
dc.contributor.authorHanson, Kenneth
dc.date.accessioned2022-11-29T15:56:30Z
dc.date.available2022-11-29T15:56:30Z
dc.date.issued2019
dc.description.abstractHere we report a method for enantioenriching BINOL using a chiral auxiliary and an excited state proton transfer (ESPT) event. Regardless of the starting enantiomeric excess (ee), after irradiation the solution reaches a photostationary state whose ee is dependent solely on the identity of the chiral auxiliary group. The enantio-enriched BINOL is easily recovered by cleaving the auxiliary group in mild conditions.
dc.identifier.citationAyad, S., Posey, V., Das, A., Montgomery, J. M., Hanson, K. (2019). Enantioenrichment of racemic BINOL by way of excited state proton transfer. Chemical Communications 55(9).
dc.identifier.issn1359-7345, 1364-548X (
dc.identifier.uriDOI https://doi.org/10.1039/C8CC07949H
dc.identifier.urihttps://hdl.handle.net/11416/959
dc.language.isoen_US
dc.publisherRoyal Society of Chemistry
dc.subjectResearch Subject Categories::NATURAL SCIENCES::Chemistry
dc.titleEnantioenrichment of racemic BINOL by way of excited state proton transfer
dc.typeArticle
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