Exceptional stability and high hydrogen uptake in hydrogen-bonded metal-organic cubes possessing ACO and AST zeolite-like topologies
Date
2009
Journal Title
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Volume Title
Publisher
American Chemical Society
Abstract
A novel approach for targeting zeolite-like metal-organic frameworks (ZMOFs) that utilizes metal-organic cubes and are regarded as double four-membered rings (d4Rs) and are composite building units (BUs) in traditional inorganic zeolites are reported. The implimentation of the new method is demonstrated by two ZMOFs with ACO and AST zeolite-like topologies constructed from d4R BUs exclusively held together by hydrogen bonds.
Description
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Keywords
Hydrogen bonding, Organometallic compounds, Zeolites
Citation
Sava, D. F., Kravtsov, V. C., Eckert, J., Eubank, J. F., Nouar, F., & Eddaoudi, M. (2009). Exceptional stability and high hydrogen uptake in hydrogen-bonded metal-organic cubes possessing ACO and AST zeolite-like topologies. Journal of the American Chemical Society, 131(30), 10394.