Exceptional stability and high hydrogen uptake in hydrogen-bonded metal-organic cubes possessing ACO and AST zeolite-like topologies

Date

2009

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

A novel approach for targeting zeolite-like metal-organic frameworks (ZMOFs) that utilizes metal-organic cubes and are regarded as double four-membered rings (d4Rs) and are composite building units (BUs) in traditional inorganic zeolites are reported. The implimentation of the new method is demonstrated by two ZMOFs with ACO and AST zeolite-like topologies constructed from d4R BUs exclusively held together by hydrogen bonds.

Description

Keywords

Hydrogen bonding, Organometallic compounds, Zeolites

Citation

Sava, D. F., Kravtsov, V. C., Eckert, J., Eubank, J. F., Nouar, F., & Eddaoudi, M. (2009). Exceptional stability and high hydrogen uptake in hydrogen-bonded metal-organic cubes possessing ACO and AST zeolite-like topologies. Journal of the American Chemical Society, 131(30), 10394.

URI

https://search.ebscohost.com/login.aspx?direct=true&AuthType=shib&db=edsgao&AN=edsgcl.207854639&site=eds-live&scope=site&custid=s5615486
 http://hdl.handle.net/11416/796

DOI

Collections

Chemistry and Physics